Early solar system aqueous activity: K isotope evidence from Allende     

Yun Jiang  Piers Koefoed  Olga Pravdivtseva  Heng Chen  Chun‐Hui Li  Fang Huang  Li‐Ping Qin  Jia Liu  Kun Wang 《Meteoritics & planetary science》2021,56(1):61-76

The alkali element K is moderately volatile and fluid mobile; thus, it can be influenced by both primary processes (evaporation and recondensation) in the solar nebula and secondary processes (thermal and aqueous alteration) in the parent body. Since these primary and secondary processes would induce different isotopic fractionations, K isotopes could become a potential tracer to distinguish them. Using recently developed methods with improved precision (0.05‰, 95% confidence interval), we systematically measured the K isotopic compositions and major/trace elemental compositions of chondritic components (18 chondrules, 3 CAIs, 2 matrices, and 5 bulks) in the carbonaceous chondrite fall Allende. Among all the components analyzed in this study, CAIs, which formed initially under high‐temperature conditions in the solar nebula and were dominated by nominally K‐free refractory minerals, have the highest K₂O content (average 0.53 wt%) and have K isotope compositions most enriched in heavy isotopes (δ⁴¹K: ?0.30 to ?0.25‰). Such an observation is consistent with previous petrologic studies that show CAIs in Allende have undergone alkali enrichment during metasomatism. In contrast, chondrules contain lower K₂O content (0.003–0.17 wt%) and generally lighter K isotope compositions (δ⁴¹K: ?0.87‰ to ?0.24‰). The matrix and bulks are nearly identical in K₂O content and K isotope compositions (0.02–0.05 wt%; δ⁴¹K: ?0.62 to ? 0.46‰), which are, as expected, right in the middle of CAIs and chondrules. This strongly indicates that most of the chondritic components of Allende suffered aqueous alteration and their K isotopic compositions are the ramification of Allende parent‐body processing instead of primary nebular signatures. Nevertheless, we propose the small K isotope fractionations observed (< 1‰) among Allende components are likely similar to the overall range of K isotopic fractionation that occurred in nebular environment. Furthermore, the K isotope compositions seen in the components of Allende in this study are consistent with MC‐ICP‐MS analyses of the components in ordinary chondrites, which also show an absence of large (10‰) isotope fractionations. This is not expected as evaporation experiments in nebular conditions suggest there should be large K isotopic fractionations. Nevertheless, possible nebular processes such as chondrules back exchanging with ambient gas when they formed could explain this lack of large K isotopic variation.  相似文献   

东北三省全面振兴的社会经济支撑能力评估     

马丽  田华征  康蕾  戚伟 《地理科学》2020,40(6):863-873

在解析支撑能力和东北问题特点的基础上，从“创新、协调、绿色、开放、共享”五大理念出发建立全面振兴社会经济支撑能力评价指标体系和综合评价方法，以地级市为单元对东北三省进行评估。研究发现：各地市社会经济支撑能力差异显著，哈大沿线核心城市的支撑能力较强，西翼城市以及朝阳、七台河、绥化、葫芦岛、铁岭、双鸭山和鹤岗等资源型城市支撑能力较弱。因此未来东北地区在振兴政策的区域分布上应有所侧重，对不同地区施以不同的振兴或扶持政策。在创新、绿色、开放方面需要集中力量重点突破，而在体制机制改革和共享服务建设方面需要全面覆盖，并重点加强黑龙江北部和辽宁、吉林西翼城市的共享能力建设。  相似文献   

环渤海地区海洋经济增长质量空间溢出效应研究   总被引：4，自引：2，他引：2  

李博  田闯  金翠  史钊源 《地理科学》2020,40(8):1266-1275

海洋经济向质量效益型转变是建设海洋强国的新要求。通过构建海洋经济?地理距离空间权重矩阵对2000—2014年环渤海地区17个沿海地级市海洋经济增长质量主体的空间交互作用及空间效应进行研究；借助空间计量模型对海洋经济增长质量空间效应影响因素进行甄别。研究表明：① 环渤海地区海洋经济增长质量主体呈显著空间相关性，存在空间交互作用；② 海洋经济增长质量存在空间溢出的正反馈效应。影响因素中对环渤海地区海洋经济增长质量的直接贡献强度排序为：海洋环境>海洋产业>海洋人才>海洋资本>海洋科技，对其他地区溢出效应影响的排序为：海洋基建>海洋人才>海洋资本。研究为环渤海地区海洋政策制定提供一定参考依据。  相似文献   

游客-环境互动视角下旅游者目的地环境恢复性效应     

朱芳  苏勤  陶云  沈惊宏 《热带地理》2020,40(4):636-648

日常生活环境和旅游目的地环境都可以为个体提供恢复的机会，不同环境的属性特征导致不同程度的恢复。为了探究环境类型与恢复性效应之间的关系及停留时间的调节作用，文章采用问卷调查方式，利用配对样本t检验和混合设计方差分析相结合的方法，探讨游客在不同环境中的恢复性效应，并对这一现象提供心理上的解释。结果表明：1）恢复体验的4个维度（放松体验、心理脱离、掌握体验、控制体验）在旅游目的地环境中的得分均高于日常生活环境。2）掌握和控制体验维度在城市旅游目的地中的变化程度高于乡村旅游目的地，两种类型目的地的放松和心理脱离维度差异较小。3）随着在目的地停留时间的延长，乡村旅游目的地放松体验和心理脱离维度变化程度高于城市旅游目的地，两种类型目的地环境恢复性效应会相互靠近。因此，游客的环境恢复性效应不仅受到环境和目的地类型的影响，同时还与游客的适应程度有关，且受到其停留时间的调节作用。  相似文献   

两株南极枝孢霉属真菌Cladosporium sp.NJF4和NJF6的次级代谢产物研究          下载免费PDF全文

常俊男  田晓清  樊成奇  黄金昌  陆亚男  韩清华 《极地研究》2020,32(1):60-67

南极因其独特的自然环境成为潜在、重要的微生物资源库,是产生新型生物活性物质和先导化合物菌株的潜在种源地,南极微生物正在成为创新药物研究新的重要资源。虽然近年来对南极微生物次级代谢产物的研究逐渐增加,但与温带和热带微生物研究相比仍处于初级阶段。对从南极普里兹湾海洋沉积物中获得的两株枝孢霉属真菌Cladosporium sp. NJF4和NJF6进行次级代谢产物分离及结构鉴定,获得20个化合物。化合物结构类型包括甾醇(1)、倍半萜类(7—8)、生物碱类(9—14)、二酮哌嗪(2—5、15—17)、芳香酸(6、18—19)等,其中倍半萜类(7—8)为首次从枝孢霉属真菌中分离得到,以上研究将为丰富南极微生物次级代谢产物库奠定一定的研究基础。  相似文献   

Salinivibrio sp.YH4胞外丝氨酸蛋白酶EYHS耐盐性及生物信息学分析          下载免费PDF全文

武翠玲  宋英达  高慧芳  张廉芸  任晨霞 《盐湖研究》2020,28(1)

摘要：目的 探讨菌株Salinivibrio sp.YH4分泌的丝氨酸蛋白酶EYHS的耐盐性及结构特征。方法 明胶底物酶谱法分析EYHS的耐盐性。应用生物信息学手段对EYHS及6种耐盐的S8家族丝氨酸蛋白酶结构特征进行分析。结果 EYHS在4 mol/L的NaCl溶液中仍具有活性，属于耐盐蛋白酶。EYHS及6种S8家族丝氨酸蛋白酶分子表面的loop区等无规则卷曲所占比例较高，α-螺旋与β-片层则主要位于酶分子内部。EYHS分子表面酸性氨基酸含量较高，且具有弱疏水内核。多序列比对发现蛋白酶的催化三联体两侧存在高度保守的基序和保守的极性氨基酸及芳香族氨基酸，并存在多个保守的Gly与Ala。同源模建和表面电荷分布显示，α螺旋和β片层围成了蛋白酶的催化腔，EYHS活性中心包含由Asp32、His65与Ser215组成的催化三联体，且催化位点区域表面静电势为负。结论 上述结构特征可能有助于耐盐丝氨酸蛋白酶EYHS在高盐环境下维持其稳定性和适度柔性，并有助于其催化功能的发挥，为深入研究耐盐丝氨酸蛋白酶的高盐环境适应性提供了一定的理论依据。  相似文献   

Correspondence between the large volcanic eruptions and ENSO events over AD 1525–2000     

Fang  Xiuqi  Zheng  Xue  Zhang  Xing 《地理学报(英文版)》2020,30(1):103-118

ENSO is an interannual mode which may be affected by external forcing, such as volcanic eruptions. Based on the reconstructed volcanic eruptions chronology and ENSO sequences, both 195 large volcanic eruptions(VEI≥4) and 398 ENSO(El Ni?o and La Ni?a) events were extracted from 1525 to 2000. An analysis of the correspondence between the large volcanic eruptions and ENSO events was performed by matching the large volcanic eruptions with the types and magnitudes of ENSO events present in the 0–2 years after the eruptions. The results show the following:(1) The percentages of ENSO events within the 3 years after the large eruptions had increased to 68.3% from 31.7% compared with those with no-eruptions in the previous 0–2 years. In addition, the ratio of El Ni?o to La Ni?a events turned from 2:3 to 1:1, and more El Ni?o events occurred in the 0 year after eruptions in the low-latitudes of the Northern Hemisphere and in the tropics but more La Ni?a events occurred in the 0 year after in the high-latitudes of the Northern Hemisphere and the Southern Hemisphere.(2) After the eruptions, the weak(W) El Ni?o events had increased by 8 percentage points and the very strong(VS) El Ni?o events had decreased by 10 percentage points; conversely, there was a decrease by 15 percentage points of the weak La Ni?a events and an increase by 11.4 percentage points of the very strong La Ni?a events. Specifically, the percentages of strong La Ni?a events increased to a peak at 1(+1) year after the eruptions.(3) The percentage of eruptions followed by single-year ENSO was the greatest. The percentage of ENSO events that occurred in the consecutive 2 years following an eruption was approximately equal to the percentage of events that occurred consecutively 3 years following an eruption, and both sets of ENSO magnitudes showed a decreasing trend.  相似文献   

城镇化与生态环境耦合的动态模拟——研究进展与展望     

崔学刚  方创琳  刘海猛  刘晓菲  李咏红 《地理学报(英文版)》2020,30(2):333-352

Urbanization and eco-environment coupling is a research hotspot.Dynamic simulation of urbanization and eco-environment coupling needs to be improved because the processes of coupling are complex and statistical methods are limited.Systems science and cross-scale coupling allow us to define the coupled urbanization and eco-environment system as an open complex giant system with multiple feedback loops.We review the current state of dynamic simulation of urbanization and eco-environment coupling and find that:(1)The use of dynamic simulation is an increasing trend,the relevant theory is being developed,and modeling processes are being improved;(2)Dynamic simulation technology has become diversified,refined,intelligent and integrated;(3)Simulation is mainly performed for three aspects of the coupling,multiple regions and multiple elements,local coupling and telecoupling,and regional synergy.However,we also found some shortcomings:(1)Basic theories are inadequately developed and insufficiently integrated;(2)The methods of unifying systems and sharing data are behind the times;(3)Coupling relations and the dynamic characteristics of the main driving elements are not fully understood or completely identified.Additionally,simulation of telecoupling does not quantify parameters and is not systemically unified,and therefore cannot be used to represent spatial synergy.In the future,we must promote communication between research networks,technology integration and data sharing to identify the processes governing change in coupled relations and in the main driving elements in urban agglomerations.Finally,we must build decision support systems to plan and ensure regional sustainable urbanization.  相似文献   

Seismic imaging of the middle and upper crust by double-difference tomography: the Haicheng earthquake (Ms 7.3) in Liaoning Province     

Que Zheng  Cai Liu  You Tian  Hong-Xiang Zhu 《应用地球物理》2018,15(1):125-136

The Haicheng earthquake (Ms 7.3) occurred in Liaoning Province (39°N–43°N, 120°E–126°E ), China on February 4, 1975. The mortality rate was only 0.02% owing to the first timely and accurate prediction, although the area affected by the earthquake was 9200 km² and covered cities with a population density of 1000 p/km². In this study, the doubledifference (DD) tomography method was used to obtain high-resolution three-dimensional (3D) P- and S-wave velocity (Vp and Vs) structures and Vp/Vs as well as the earthquake locations. Tomography results suggest that velocity structure at shallow depth coincides well with topography and sediment thickness. The earthquake locations form a northwest-striking zone associated with the Jinzhou(JZ) Fault and a northeast-striking zone associated with the Haichenghe-Dayanghe (HD) Fault, and suggest that the JZ Fault consists of three faults and the Ms 7.3 Haicheng earthquake originated at the intersection of the JZ and the Faults. Lowvelocity zones (LVZs) with low Vp/Vs are observed at 15–20 km depth beneath the Haicheng (HC) region. We interpret the LVZs in the middle crust as regions of fluids, suggesting rock dehydration at high temperatures. The LVZs and low Vp/Vs in the upper crust are attributed to groundwater-filled cracks and pores. We believe that large crustal earthquakes in this area are caused by the combination of faulting and fluid movement in the middle crust.  相似文献   

Simulations of the Impact of Lakes on Local and Regional Climate Over the Tibetan Plateau     

Lingjing Zhu  Xin Liu  Lei Tian  Qunhui Zhang 《大气与海洋》2018,56(4):230-239

ABSTRACT

Because of the high elevation and complex topography of the Tibetan Plateau (TP), the role of lakes in the climate system over the Tibetan Plateau is not well understood. For this study, we investigated the impact of lake processes on local and regional climate using the Weather Research and Forecasting (WRF) model, which includes a one-dimensional physically based lake model. The first simulation with the WRF model was performed for the TP over the 2000–2010 period, and the second was carried out during the same period but with the lakes filled with nearby land-use types. Results with the lake simulation show that the model captures the spatial and temporal patterns of annual mean precipitation and temperature well over the TP. Through comparison of the two simulations, we found that the TP lakes mainly cool the near-surface air, inducing a decreasing sensible heat flux for the entire year. Meanwhile, stronger evaporation produced by the lakes is found in the fall. During the summer, the cooling effect of the lakes decreases precipitation in the surrounding area and generates anomalous circulation patterns. In conclusion, the TP lakes cool the near-surface atmosphere most of the time, weaken the sensible heat flux, and strengthen the latent heat flux, resulting in changes in mesoscale precipitation and regional-scale circulation.  相似文献